Regioselective hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium

Iwao Ojila; Miyoko Kumagai

doi:10.1016/S0022-328X(00)93622-2

Regioselective hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium

Iwao Ojila
, Miyoko Kumagai

Chemistry

Stony Brook University

Sagami Chemical Research Institute

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium was found to proceed smoothly at 80-130°C to give 3-methylbuten-2-ylsilane (major) and 2-methylbuten-2-ylsilane (minor). A possible mechanism of the reaction is proposed.

Original language	English
Pages (from-to)	C6-C10
Journal	Journal of Organometallic Chemistry
Volume	134
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)93622-2
State	Published - Jul 5 1977

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title = "Regioselective hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium",

abstract = "Hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium was found to proceed smoothly at 80-130°C to give 3-methylbuten-2-ylsilane (major) and 2-methylbuten-2-ylsilane (minor). A possible mechanism of the reaction is proposed.",

author = "Iwao Ojila and Miyoko Kumagai",

year = "1977",

month = jul,

day = "5",

doi = "10.1016/S0022-328X(00)93622-2",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Regioselective hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium

AU - Ojila, Iwao

AU - Kumagai, Miyoko

PY - 1977/7/5

Y1 - 1977/7/5

N2 - Hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium was found to proceed smoothly at 80-130°C to give 3-methylbuten-2-ylsilane (major) and 2-methylbuten-2-ylsilane (minor). A possible mechanism of the reaction is proposed.

AB - Hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium was found to proceed smoothly at 80-130°C to give 3-methylbuten-2-ylsilane (major) and 2-methylbuten-2-ylsilane (minor). A possible mechanism of the reaction is proposed.

UR - https://www.scopus.com/pages/publications/49449127881

U2 - 10.1016/S0022-328X(00)93622-2

DO - 10.1016/S0022-328X(00)93622-2

M3 - Article

SN - 0022-328X

VL - 134

SP - C6-C10

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Regioselective hydrosilylation of isoprene catalyzed by tris(triphenylphosphine)chlororhodium

Abstract

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