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Shear wave propagation in a liquid crystal: An inelastic X-ray scattering study

  • S. T. Lynch
  • , A. De Francesco
  • , L. Scaccia
  • , A. Suvorov
  • , Y. Q. Cai
  • , D. M. Agra-Kooijman
  • , L. L. Sharpnack
  • , Satyendra Kumar
  • , A. Cunsolo

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

We investigated the spectrum of density fluctuations of a liquid crystal, CB7CB, in two different orientations by using high-resolution inelastic x-ray scattering. Our analysis, based on Bayesian principles, revealed that high-frequency collective excitations propagate through this mesoscale-ordered sample in a peculiar manner that lies somewhere between those observed in liquids and crystalline systems. Interestingly, when we probed longer length scales, a more pronounced solid-like response emerged. This was mainly characterized by anomalously sharp inelastic excitations and the onset of shear mode propagation. Comparison with previous x-ray diffraction results suggests a correlation between the observed behavior and the mesogen arrangement.

Original languageEnglish
Article number234505
JournalJournal of Chemical Physics
Volume160
Issue number23
DOIs
StatePublished - Jun 21 2024

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