Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO3@SiO2/PVDF layers and BNNSs/PVDF-PMMA layers

Qinzhao Sun; Jiping Wang; Haonan Sun; Liqiang He; Lixue Zhang; Pu Mao; Xiaoxiao zhang; Fang Kang; Zepeng Wang; Ruirui Kang; Lin Zhang

doi:10.1016/j.compositesa.2021.106546

Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO₃@SiO₂/PVDF layers and BNNSs/PVDF-PMMA layers

Qinzhao Sun
, Jiping Wang
, Haonan Sun
, Liqiang He
, Lixue Zhang
, Pu Mao
, Xiaoxiao zhang
, Fang Kang
, Zepeng Wang
, Ruirui Kang
, Lin Zhang

Department of Biomedical Engineering

University at Buffalo

Xi'an Jiaotong University
Nanchang Hangkong University

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The enhancement of the energy density and efficiency for polymer-based nanocomposites is advantageous for promoting their practical application in miniaturization and integration of dielectric capacitors. In this work, a class of newly designed layer-structured polymer-based nanocomposites based on BaTiO₃@SiO₂/PVDF dielectric layer as the central layer and BNNSs/PVDF-PMMA layers as the outer layers were prepared. By reasonably adjusting the dielectric properties of a BaTiO₃@SiO₂/PVDF dielectric layers and BNNSs/PVDF-PMMA insulating layers, the layer-structured nanocomposites exhibits simultaneously high discharge density of 20.1 J/cm³ and high efficiency of 76% under an electric field of 507 MV/m. A series of dielectric analyses and simulation results indicate that the appropriate dielectric differences redistribute the electric filed in the layer-structured nanocomposites, which relieves the electric field strength in the dielectric layer and enhances the electric breakdown strength of nanocomposites. This work can provide an effect strategy to design polymer-based nanocomposites with significantly energy storage performance.

Original language	English
Article number	106546
Journal	Composites Part A: Applied Science and Manufacturing
Volume	149
DOIs	https://doi.org/10.1016/j.compositesa.2021.106546
State	Published - Oct 2021

Keywords

A. Polymer-based nanocomposites (PMCs)
A. Thin films
B. Electrical properties
Dielectric differences

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Sun, Q., Wang, J., Sun, H., He, L., Zhang, L., Mao, P., zhang, X., Kang, F., Wang, Z., Kang, R., & Zhang, L. (2021). Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO₃@SiO₂/PVDF layers and BNNSs/PVDF-PMMA layers. Composites Part A: Applied Science and Manufacturing, 149, Article 106546. https://doi.org/10.1016/j.compositesa.2021.106546

@article{54d806a1badd4e17b514b9708c9d901f,

title = "Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO3@SiO2/PVDF layers and BNNSs/PVDF-PMMA layers",

abstract = "The enhancement of the energy density and efficiency for polymer-based nanocomposites is advantageous for promoting their practical application in miniaturization and integration of dielectric capacitors. In this work, a class of newly designed layer-structured polymer-based nanocomposites based on BaTiO3@SiO2/PVDF dielectric layer as the central layer and BNNSs/PVDF-PMMA layers as the outer layers were prepared. By reasonably adjusting the dielectric properties of a BaTiO3@SiO2/PVDF dielectric layers and BNNSs/PVDF-PMMA insulating layers, the layer-structured nanocomposites exhibits simultaneously high discharge density of 20.1 J/cm3 and high efficiency of 76\% under an electric field of 507 MV/m. A series of dielectric analyses and simulation results indicate that the appropriate dielectric differences redistribute the electric filed in the layer-structured nanocomposites, which relieves the electric field strength in the dielectric layer and enhances the electric breakdown strength of nanocomposites. This work can provide an effect strategy to design polymer-based nanocomposites with significantly energy storage performance.",

keywords = "A. Polymer-based nanocomposites (PMCs), A. Thin films, B. Electrical properties, Dielectric differences",

author = "Qinzhao Sun and Jiping Wang and Haonan Sun and Liqiang He and Lixue Zhang and Pu Mao and Xiaoxiao zhang and Fang Kang and Zepeng Wang and Ruirui Kang and Lin Zhang",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = oct,

doi = "10.1016/j.compositesa.2021.106546",

language = "English",

volume = "149",

journal = "Composites Part A: Applied Science and Manufacturing",

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Sun, Q, Wang, J, Sun, H, He, L, Zhang, L, Mao, P, zhang, X, Kang, F, Wang, Z, Kang, R & Zhang, L 2021, 'Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO₃@SiO₂/PVDF layers and BNNSs/PVDF-PMMA layers', Composites Part A: Applied Science and Manufacturing, vol. 149, 106546. https://doi.org/10.1016/j.compositesa.2021.106546

Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO₃@SiO₂/PVDF layers and BNNSs/PVDF-PMMA layers. / Sun, Qinzhao; Wang, Jiping; Sun, Haonan et al.
In: Composites Part A: Applied Science and Manufacturing, Vol. 149, 106546, 10.2021.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Simultaneously enhanced energy density and discharge efficiency of layer-structured nanocomposites by reasonably designing dielectric differences between BaTiO3@SiO2/PVDF layers and BNNSs/PVDF-PMMA layers

AU - Sun, Qinzhao

AU - Wang, Jiping

AU - Sun, Haonan

AU - He, Liqiang

AU - Zhang, Lixue

AU - Mao, Pu

AU - zhang, Xiaoxiao

AU - Kang, Fang

AU - Wang, Zepeng

AU - Kang, Ruirui

AU - Zhang, Lin

PY - 2021/10

Y1 - 2021/10

N2 - The enhancement of the energy density and efficiency for polymer-based nanocomposites is advantageous for promoting their practical application in miniaturization and integration of dielectric capacitors. In this work, a class of newly designed layer-structured polymer-based nanocomposites based on BaTiO3@SiO2/PVDF dielectric layer as the central layer and BNNSs/PVDF-PMMA layers as the outer layers were prepared. By reasonably adjusting the dielectric properties of a BaTiO3@SiO2/PVDF dielectric layers and BNNSs/PVDF-PMMA insulating layers, the layer-structured nanocomposites exhibits simultaneously high discharge density of 20.1 J/cm3 and high efficiency of 76% under an electric field of 507 MV/m. A series of dielectric analyses and simulation results indicate that the appropriate dielectric differences redistribute the electric filed in the layer-structured nanocomposites, which relieves the electric field strength in the dielectric layer and enhances the electric breakdown strength of nanocomposites. This work can provide an effect strategy to design polymer-based nanocomposites with significantly energy storage performance.

AB - The enhancement of the energy density and efficiency for polymer-based nanocomposites is advantageous for promoting their practical application in miniaturization and integration of dielectric capacitors. In this work, a class of newly designed layer-structured polymer-based nanocomposites based on BaTiO3@SiO2/PVDF dielectric layer as the central layer and BNNSs/PVDF-PMMA layers as the outer layers were prepared. By reasonably adjusting the dielectric properties of a BaTiO3@SiO2/PVDF dielectric layers and BNNSs/PVDF-PMMA insulating layers, the layer-structured nanocomposites exhibits simultaneously high discharge density of 20.1 J/cm3 and high efficiency of 76% under an electric field of 507 MV/m. A series of dielectric analyses and simulation results indicate that the appropriate dielectric differences redistribute the electric filed in the layer-structured nanocomposites, which relieves the electric field strength in the dielectric layer and enhances the electric breakdown strength of nanocomposites. This work can provide an effect strategy to design polymer-based nanocomposites with significantly energy storage performance.

KW - A. Polymer-based nanocomposites (PMCs)

KW - A. Thin films

KW - B. Electrical properties

KW - Dielectric differences

UR - https://www.scopus.com/pages/publications/85110202712

U2 - 10.1016/j.compositesa.2021.106546

DO - 10.1016/j.compositesa.2021.106546

M3 - Article

SN - 1359-835X

VL - 149

JO - Composites Part A: Applied Science and Manufacturing

JF - Composites Part A: Applied Science and Manufacturing

M1 - 106546

ER -