Single crystal X-ray diffraction study on high-prebure phase of KHCO3

K. Komatsu; H. Kagi; T. Nagai; T. Kuribayashi; J. B. Parise; Y. Kudoh

Single crystal X-ray diffraction study on high-prebure phase of KHCO3

K. Komatsu
, H. Kagi
, T. Nagai
, T. Kuribayashi
, J. B. Parise
, Y. Kudoh

Geosciences

Stony Brook University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The monoclinic and triclinic high-prebure phases of KHCO₃ were identified for the first time by in-situ high-prebure single crystal X-ray analysis. These monoclinic and triclinic lattices are different from three previously identified phases, I-III. We propose that the monoclinic and triclinic variants be called phase IV and V, respectively. The two lattices are superimposed along a∗with a∗IV = 2 x a∗V, i.e., the bc plane is common in both lattices in real space. The space group of phase IV is to P21/b11 with unit cell parameters of a = 10.024(3) A, b = 6.912(5) A, c = 4.1868(11) A, α = 115.92(4)°, and V = 260.9(2) A₃. The crystal structure of phase IV, without hydrogen site, was refined.

Original language	English
Title of host publication	Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology
Editors	Eckhard Dinjus
Publisher	Karlsruhe Forschungszentrum Karlsruhe gmbH
ISBN (Electronic)	9783923704491
State	Published - 2005
Event	International Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology - Karlsruhe, Germany Duration: Jun 27 2005 → Jul 1 2005

Publication series

Name	Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology

Conference

Conference	International Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology
Country/Territory	Germany
City	Karlsruhe
Period	06/27/05 → 07/1/05

Cite this

Komatsu, K., Kagi, H., Nagai, T., Kuribayashi, T., Parise, J. B., & Kudoh, Y. (2005). Single crystal X-ray diffraction study on high-prebure phase of KHCO3. In E. Dinjus (Ed.), Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology (Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology). Karlsruhe Forschungszentrum Karlsruhe gmbH.

Komatsu, K. ; Kagi, H. ; Nagai, T. et al. / Single crystal X-ray diffraction study on high-prebure phase of KHCO3. Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology. editor / Eckhard Dinjus. Karlsruhe Forschungszentrum Karlsruhe gmbH, 2005. (Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology).

@inproceedings{9873717d01eb408299384fe932da96e6,

title = "Single crystal X-ray diffraction study on high-prebure phase of KHCO3",

abstract = "The monoclinic and triclinic high-prebure phases of KHCO3 were identified for the first time by in-situ high-prebure single crystal X-ray analysis. These monoclinic and triclinic lattices are different from three previously identified phases, I-III. We propose that the monoclinic and triclinic variants be called phase IV and V, respectively. The two lattices are superimposed along a∗with a∗IV = 2 x a∗V, i.e., the bc plane is common in both lattices in real space. The space group of phase IV is to P21/b11 with unit cell parameters of a = 10.024(3) A, b = 6.912(5) A, c = 4.1868(11) A, α = 115.92(4)°, and V = 260.9(2) A3. The crystal structure of phase IV, without hydrogen site, was refined.",

author = "K. Komatsu and H. Kagi and T. Nagai and T. Kuribayashi and Parise, \{J. B.\} and Y. Kudoh",

year = "2005",

language = "English",

series = "Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology",

publisher = "Karlsruhe Forschungszentrum Karlsruhe gmbH",

editor = "Eckhard Dinjus",

booktitle = "Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology",

note = "International Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology ; Conference date: 27-06-2005 Through 01-07-2005",

}

Komatsu, K, Kagi, H, Nagai, T, Kuribayashi, T, Parise, JB & Kudoh, Y 2005, Single crystal X-ray diffraction study on high-prebure phase of KHCO3. in E Dinjus (ed.), Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology. Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology, Karlsruhe Forschungszentrum Karlsruhe gmbH, International Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology, Karlsruhe, Germany, 06/27/05.

Single crystal X-ray diffraction study on high-prebure phase of KHCO3. / Komatsu, K.; Kagi, H.; Nagai, T. et al.
Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology. ed. / Eckhard Dinjus. Karlsruhe Forschungszentrum Karlsruhe gmbH, 2005. (Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Single crystal X-ray diffraction study on high-prebure phase of KHCO3

AU - Komatsu, K.

AU - Kagi, H.

AU - Nagai, T.

AU - Kuribayashi, T.

AU - Parise, J. B.

AU - Kudoh, Y.

PY - 2005

Y1 - 2005

N2 - The monoclinic and triclinic high-prebure phases of KHCO3 were identified for the first time by in-situ high-prebure single crystal X-ray analysis. These monoclinic and triclinic lattices are different from three previously identified phases, I-III. We propose that the monoclinic and triclinic variants be called phase IV and V, respectively. The two lattices are superimposed along a∗with a∗IV = 2 x a∗V, i.e., the bc plane is common in both lattices in real space. The space group of phase IV is to P21/b11 with unit cell parameters of a = 10.024(3) A, b = 6.912(5) A, c = 4.1868(11) A, α = 115.92(4)°, and V = 260.9(2) A3. The crystal structure of phase IV, without hydrogen site, was refined.

AB - The monoclinic and triclinic high-prebure phases of KHCO3 were identified for the first time by in-situ high-prebure single crystal X-ray analysis. These monoclinic and triclinic lattices are different from three previously identified phases, I-III. We propose that the monoclinic and triclinic variants be called phase IV and V, respectively. The two lattices are superimposed along a∗with a∗IV = 2 x a∗V, i.e., the bc plane is common in both lattices in real space. The space group of phase IV is to P21/b11 with unit cell parameters of a = 10.024(3) A, b = 6.912(5) A, c = 4.1868(11) A, α = 115.92(4)°, and V = 260.9(2) A3. The crystal structure of phase IV, without hydrogen site, was refined.

UR - https://www.scopus.com/pages/publications/84966632279

M3 - Conference contribution

T3 - Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology

BT - Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology

A2 - Dinjus, Eckhard

PB - Karlsruhe Forschungszentrum Karlsruhe gmbH

T2 - International Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology

Y2 - 27 June 2005 through 1 July 2005

ER -

Komatsu K, Kagi H, Nagai T, Kuribayashi T, Parise JB, Kudoh Y. Single crystal X-ray diffraction study on high-prebure phase of KHCO3. In Dinjus E, editor, Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology. Karlsruhe Forschungszentrum Karlsruhe gmbH. 2005. (Joint 20th AIRAPT and 43rd EHPRG International Conference on High Pressure Science and Technology).

Single crystal X-ray diffraction study on high-prebure phase of KHCO3

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