Solid-state coexistence of {Zr12} and {Zr6} zirconium oxocarboxylate clusters

Iurie L. Malaestean; Meliha Kutluca Alici; Claire Besson; Arkady Ellern; Paul Kögerler

doi:10.1039/c3ce41829d

Solid-state coexistence of {Zr₁₂} and {Zr₆} zirconium oxocarboxylate clusters

Iurie L. Malaestean
, Meliha Kutluca Alici
, Claire Besson
, Arkady Ellern
, Paul Kögerler

Chemistry

Binghamton University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Ligand metathesis, Co(ii) coordination, and partial condensation reactions of an archetypal {Zr₆} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr₆O₈} and {Zr₁₂O₂₂}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr₆O₈}-based product.

Original language	English
Pages (from-to)	43-46
Number of pages	4
Journal	CrystEngComm
Volume	16
Issue number	1
DOIs	https://doi.org/10.1039/c3ce41829d
State	Published - Jan 7 2014

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title = "Solid-state coexistence of \{Zr12\} and \{Zr6\} zirconium oxocarboxylate clusters",

abstract = "Ligand metathesis, Co(ii) coordination, and partial condensation reactions of an archetypal \{Zr6\} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks \{Zr6O8\} and \{Zr12O22\}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the \{Zr6O8\}-based product.",

author = "Malaestean, \{Iurie L.\} and Alici, \{Meliha Kutluca\} and Claire Besson and Arkady Ellern and Paul K{\"o}gerler",

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T1 - Solid-state coexistence of {Zr12} and {Zr6} zirconium oxocarboxylate clusters

AU - Malaestean, Iurie L.

AU - Alici, Meliha Kutluca

AU - Besson, Claire

AU - Ellern, Arkady

AU - Kögerler, Paul

PY - 2014/1/7

Y1 - 2014/1/7

N2 - Ligand metathesis, Co(ii) coordination, and partial condensation reactions of an archetypal {Zr6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.

AB - Ligand metathesis, Co(ii) coordination, and partial condensation reactions of an archetypal {Zr6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.

UR - https://www.scopus.com/pages/publications/84888401596

U2 - 10.1039/c3ce41829d

DO - 10.1039/c3ce41829d

M3 - Article

SN - 1466-8033

VL - 16

SP - 43

EP - 46

JO - CrystEngComm

JF - CrystEngComm

IS - 1

ER -

Solid-state coexistence of {Zr₁₂} and {Zr₆} zirconium oxocarboxylate clusters

Abstract

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