Solvothermal synthesis and characterization of a layered pyridinium vanadate, (C5H6N)V3O7

Samuel T. Lutta; Natasha A. Chernova; Peter Y. Zavalij; M. Stanley Whittingham

doi:10.1039/b302534a

Solvothermal synthesis and characterization of a layered pyridinium vanadate, (C₅H₆N)V₃O₇

Samuel T. Lutta
, Natasha A. Chernova
, Peter Y. Zavalij
, M. Stanley Whittingham

Chemistry

Binghamton University

State University of New York Binghamton University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A new layered vanadium oxide, (C₅H₅NH)V₃O₇, has been synthesized by a solvothermal process at 200°C; this is the first vanadium oxide to have an aromatic intercalate between the V₃O₇ sheets, and it has a monoclinic structure with space group P2₁ and lattice parameters a = 7.5296(6) Å, b = 6.6592(8) Å, c = 10.1513(12) Å and β = 94.460(2)°.

Original language	English
Pages (from-to)	1424-1428
Number of pages	5
Journal	Journal of Materials Chemistry
Volume	13
Issue number	6
DOIs	https://doi.org/10.1039/b302534a
State	Published - Jun 1 2003

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title = "Solvothermal synthesis and characterization of a layered pyridinium vanadate, (C5H6N)V3O7",

abstract = "A new layered vanadium oxide, (C5H5NH)V3O7, has been synthesized by a solvothermal process at 200°C; this is the first vanadium oxide to have an aromatic intercalate between the V3O7 sheets, and it has a monoclinic structure with space group P21 and lattice parameters a = 7.5296(6) {\AA}, b = 6.6592(8) {\AA}, c = 10.1513(12) {\AA} and β = 94.460(2)°.",

author = "Lutta, \{Samuel T.\} and Chernova, \{Natasha A.\} and Zavalij, \{Peter Y.\} and Whittingham, \{M. Stanley\}",

year = "2003",

month = jun,

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doi = "10.1039/b302534a",

language = "English",

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journal = "Journal of Materials Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Solvothermal synthesis and characterization of a layered pyridinium vanadate, (C5H6N)V3O7

AU - Lutta, Samuel T.

AU - Chernova, Natasha A.

AU - Zavalij, Peter Y.

AU - Whittingham, M. Stanley

PY - 2003/6/1

Y1 - 2003/6/1

N2 - A new layered vanadium oxide, (C5H5NH)V3O7, has been synthesized by a solvothermal process at 200°C; this is the first vanadium oxide to have an aromatic intercalate between the V3O7 sheets, and it has a monoclinic structure with space group P21 and lattice parameters a = 7.5296(6) Å, b = 6.6592(8) Å, c = 10.1513(12) Å and β = 94.460(2)°.

AB - A new layered vanadium oxide, (C5H5NH)V3O7, has been synthesized by a solvothermal process at 200°C; this is the first vanadium oxide to have an aromatic intercalate between the V3O7 sheets, and it has a monoclinic structure with space group P21 and lattice parameters a = 7.5296(6) Å, b = 6.6592(8) Å, c = 10.1513(12) Å and β = 94.460(2)°.

UR - https://www.scopus.com/pages/publications/0038792252

U2 - 10.1039/b302534a

DO - 10.1039/b302534a

M3 - Article

SN - 0959-9428

VL - 13

SP - 1424

EP - 1428

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 6

ER -

Solvothermal synthesis and characterization of a layered pyridinium vanadate, (C₅H₆N)V₃O₇

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