Stable pseudo[3]rotaxanes with strong positive binding cooperativity based on shape-persistent aromatic oligoamide macrocycles

Thomas A. Sobiech; Yulong Zhong; Laura S. Sánchez B.; Brice Kauffmann; Jillian K. McGrath; Christina Scalzo; Daniel P. Miller; Ivan Huc; Eva Zurek; Yann Ferrand; Bing Gong

doi:10.1039/d1cc05193h

Stable pseudo[3]rotaxanes with strong positive binding cooperativity based on shape-persistent aromatic oligoamide macrocycles

Thomas A. Sobiech
, Yulong Zhong
, Laura S. Sánchez B.
, Brice Kauffmann
, Jillian K. McGrath
, Christina Scalzo
, Daniel P. Miller
, Ivan Huc
, Eva Zurek
, Yann Ferrand
, Bing Gong

Chemistry

University at Buffalo

SUNY Buffalo
Hofstra University
Université de Bordeaux
Ludwig Maximilian University of Munich

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

New aromatic oligoamide macrocycles withC₃-symmetry bind a bipyridinium guest (G) to form compact pseudo[3]rotaxanes involving interesting enthalpic and entropic contributions. The observed high stabilities and strong positive binding cooperativity are found in few other host-guest systems.

Original language	English
Pages (from-to)	11645-11648
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	88
DOIs	https://doi.org/10.1039/d1cc05193h
State	Published - Nov 14 2021

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10.1039/d1cc05193h

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title = "Stable pseudo[3]rotaxanes with strong positive binding cooperativity based on shape-persistent aromatic oligoamide macrocycles",

abstract = "New aromatic oligoamide macrocycles withC3-symmetry bind a bipyridinium guest (G) to form compact pseudo[3]rotaxanes involving interesting enthalpic and entropic contributions. The observed high stabilities and strong positive binding cooperativity are found in few other host-guest systems.",

author = "Sobiech, \{Thomas A.\} and Yulong Zhong and \{S{\'a}nchez B.\}, \{Laura S.\} and Brice Kauffmann and McGrath, \{Jillian K.\} and Christina Scalzo and Miller, \{Daniel P.\} and Ivan Huc and Eva Zurek and Yann Ferrand and Bing Gong",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = nov,

day = "14",

doi = "10.1039/d1cc05193h",

language = "English",

volume = "57",

pages = "11645--11648",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "88",

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TY - JOUR

T1 - Stable pseudo[3]rotaxanes with strong positive binding cooperativity based on shape-persistent aromatic oligoamide macrocycles

AU - Sobiech, Thomas A.

AU - Zhong, Yulong

AU - Sánchez B., Laura S.

AU - Kauffmann, Brice

AU - McGrath, Jillian K.

AU - Scalzo, Christina

AU - Miller, Daniel P.

AU - Huc, Ivan

AU - Zurek, Eva

AU - Ferrand, Yann

AU - Gong, Bing

PY - 2021/11/14

Y1 - 2021/11/14

N2 - New aromatic oligoamide macrocycles withC3-symmetry bind a bipyridinium guest (G) to form compact pseudo[3]rotaxanes involving interesting enthalpic and entropic contributions. The observed high stabilities and strong positive binding cooperativity are found in few other host-guest systems.

AB - New aromatic oligoamide macrocycles withC3-symmetry bind a bipyridinium guest (G) to form compact pseudo[3]rotaxanes involving interesting enthalpic and entropic contributions. The observed high stabilities and strong positive binding cooperativity are found in few other host-guest systems.

UR - https://www.scopus.com/pages/publications/85118670430

U2 - 10.1039/d1cc05193h

DO - 10.1039/d1cc05193h

M3 - Article

C2 - 34693416

SN - 1359-7345

VL - 57

SP - 11645

EP - 11648

JO - Chemical Communications

JF - Chemical Communications

IS - 88

ER -

Stable pseudo[3]rotaxanes with strong positive binding cooperativity based on shape-persistent aromatic oligoamide macrocycles

Abstract

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