Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal

Zheng Zhou; Yikun Zhu; Jesús M. Fernández-García; Zheng Wei; Israel Fernández; Marina A. Petrukhina; Nazario Martín

doi:10.1039/d2cc00971d

Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal

Zheng Zhou
, Yikun Zhu
, Jesús M. Fernández-García
, Zheng Wei
, Israel Fernández
, Marina A. Petrukhina
, Nazario Martín

Chemistry

University at Albany

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The chemical reduction of a corannulene-based molecular nanographene, C₇₆H₆₄ (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.

Original language	English
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/d2cc00971d
State	Accepted/In press - 2022

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@article{d792a496efe4436497f257404e5e592e,

title = "Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal",

abstract = "The chemical reduction of a corannulene-based molecular nanographene, C76H64 (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.",

author = "Zheng Zhou and Yikun Zhu and Fern{\'a}ndez-Garc{\'i}a, \{Jes{\'u}s M.\} and Zheng Wei and Israel Fern{\'a}ndez and Petrukhina, \{Marina A.\} and Nazario Mart{\'i}n",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

year = "2022",

doi = "10.1039/d2cc00971d",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

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TY - JOUR

T1 - Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal

AU - Zhou, Zheng

AU - Zhu, Yikun

AU - Fernández-García, Jesús M.

AU - Wei, Zheng

AU - Fernández, Israel

AU - Petrukhina, Marina A.

AU - Martín, Nazario

PY - 2022

Y1 - 2022

N2 - The chemical reduction of a corannulene-based molecular nanographene, C76H64 (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.

AB - The chemical reduction of a corannulene-based molecular nanographene, C76H64 (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.

UR - https://www.scopus.com/pages/publications/85128201040

U2 - 10.1039/d2cc00971d

DO - 10.1039/d2cc00971d

M3 - Article

C2 - 35353101

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Stepwise reduction of a corannulene-based helical molecular nanographene with Na metal

Abstract

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