Structural studies on polynuclear osmium carbonyl hydrides. 15.1 Preparation and x-ray crystal structure of (¼-H) Os3(CO)10(¼-NHSO2C6H4Me), a complex with an Os(¼-H)(¼-N)Os bridge

Melvyn Rowen Churchill; Fredrick J. Hollander; John R. Shapley; Jerome B. Keister

doi:10.1021/ic50207a033

Structural studies on polynuclear osmium carbonyl hydrides. 15.¹ Preparation and x-ray crystal structure of (¼-H) Os₃(CO)₁₀(¼-NHSO₂C₆H₄Me), a complex with an Os(¼-H)(¼-N)Os bridge

Melvyn Rowen Churchill
, Fredrick J. Hollander
, John R. Shapley
, Jerome B. Keister

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The complex (¼-H)Os₃(CO)₁₀(¼-NHSO₂C₆H₄Me) has been synthesized from (¼-H)₂Os₃(CO)₁₀ and MeC₆H₄SO₂N₃. This species crystallizes in the triclinic space group PI with a = 8.246 (1) Å, b = 8.668 (1) Å, c = 18.572 (3) Å, α = 89.92 (1)°, β = 98.61 (1)°, γ = 113.05 (1)°, V= 1205.4 (2) Å³, P_calcd = 2.82 g cm^-3 for mol wt 1021.95, and Z = 2. Diffraction data (4.5° < 26 < 50° Mo Kα) were collected with a Syntex P2₁ diffractometer, and the structure was solved by standard Patterson, Fourier, and least-squares refinement techniques.

Original language	English
Pages (from-to)	1272-1277
Number of pages	6
Journal	Inorganic Chemistry
Volume	19
Issue number	5
DOIs	https://doi.org/10.1021/ic50207a033
State	Published - 1980

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@article{99b0758e9f1149b9adfcf2a6edcef7ef,

title = "Structural studies on polynuclear osmium carbonyl hydrides. 15.1 Preparation and x-ray crystal structure of (¼-H) Os3(CO)10(¼-NHSO2C6H4Me), a complex with an Os(¼-H)(¼-N)Os bridge",

abstract = "The complex (¼-H)Os3(CO)10(¼-NHSO2C6H4Me) has been synthesized from (¼-H)2Os3(CO)10 and MeC6H4SO2N3. This species crystallizes in the triclinic space group PI with a = 8.246 (1) {\AA}, b = 8.668 (1) {\AA}, c = 18.572 (3) {\AA}, α = 89.92 (1)°, β = 98.61 (1)°, γ = 113.05 (1)°, V= 1205.4 (2) {\AA}3, Pcalcd = 2.82 g cm-3 for mol wt 1021.95, and Z = 2. Diffraction data (4.5° < 26 < 50° Mo Kα) were collected with a Syntex P21 diffractometer, and the structure was solved by standard Patterson, Fourier, and least-squares refinement techniques.",

author = "Churchill, \{Melvyn Rowen\} and Hollander, \{Fredrick J.\} and Shapley, \{John R.\} and Keister, \{Jerome B.\}",

year = "1980",

doi = "10.1021/ic50207a033",

language = "English",

volume = "19",

pages = "1272--1277",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "5",

}

Structural studies on polynuclear osmium carbonyl hydrides. 15.¹ Preparation and x-ray crystal structure of (¼-H) Os₃(CO)₁₀(¼-NHSO₂C₆H₄Me), a complex with an Os(¼-H)(¼-N)Os bridge. / Churchill, Melvyn Rowen; Hollander, Fredrick J.; Shapley, John R. et al.
In: Inorganic Chemistry, Vol. 19, No. 5, 1980, p. 1272-1277.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Structural studies on polynuclear osmium carbonyl hydrides. 15.1 Preparation and x-ray crystal structure of (¼-H) Os3(CO)10(¼-NHSO2C6H4Me), a complex with an Os(¼-H)(¼-N)Os bridge

AU - Churchill, Melvyn Rowen

AU - Hollander, Fredrick J.

AU - Shapley, John R.

AU - Keister, Jerome B.

PY - 1980

Y1 - 1980

N2 - The complex (¼-H)Os3(CO)10(¼-NHSO2C6H4Me) has been synthesized from (¼-H)2Os3(CO)10 and MeC6H4SO2N3. This species crystallizes in the triclinic space group PI with a = 8.246 (1) Å, b = 8.668 (1) Å, c = 18.572 (3) Å, α = 89.92 (1)°, β = 98.61 (1)°, γ = 113.05 (1)°, V= 1205.4 (2) Å3, Pcalcd = 2.82 g cm-3 for mol wt 1021.95, and Z = 2. Diffraction data (4.5° < 26 < 50° Mo Kα) were collected with a Syntex P21 diffractometer, and the structure was solved by standard Patterson, Fourier, and least-squares refinement techniques.

AB - The complex (¼-H)Os3(CO)10(¼-NHSO2C6H4Me) has been synthesized from (¼-H)2Os3(CO)10 and MeC6H4SO2N3. This species crystallizes in the triclinic space group PI with a = 8.246 (1) Å, b = 8.668 (1) Å, c = 18.572 (3) Å, α = 89.92 (1)°, β = 98.61 (1)°, γ = 113.05 (1)°, V= 1205.4 (2) Å3, Pcalcd = 2.82 g cm-3 for mol wt 1021.95, and Z = 2. Diffraction data (4.5° < 26 < 50° Mo Kα) were collected with a Syntex P21 diffractometer, and the structure was solved by standard Patterson, Fourier, and least-squares refinement techniques.

UR - https://www.scopus.com/pages/publications/1542454826

U2 - 10.1021/ic50207a033

DO - 10.1021/ic50207a033

M3 - Article

SN - 0020-1669

VL - 19

SP - 1272

EP - 1277

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

Structural studies on polynuclear osmium carbonyl hydrides. 15.¹ Preparation and x-ray crystal structure of (¼-H) Os₃(CO)₁₀(¼-NHSO₂C₆H₄Me), a complex with an Os(¼-H)(¼-N)Os bridge

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