Supramolecular organization of the organic-inorganic hybrid [{p-(CH3)2NH—C6H4—NH3}2Cl][BiI6]: assembly of a three-dimensional structure via covalent and non-covalent interactions

T. A. Shestimerova; N. A. Golubev; A. V. Grigorieva; M. A. Bykov; Z. Wei; E. V. Dikarev; A. V. Shevelkov

doi:10.1007/s11172-021-3054-1

Supramolecular organization of the organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆]: assembly of a three-dimensional structure via covalent and non-covalent interactions

T. A. Shestimerova
, N. A. Golubev
, A. V. Grigorieva
, M. A. Bykov
, Z. Wei
, E. V. Dikarev
, A. V. Shevelkov

Chemistry

University at Albany

Lomonosov Moscow State University
SUNY Albany

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A new organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆] was synthesized and its crystal structure was established. The hybrid consists of an inorganic anion [BiI₆]³⁻ and an organic cation [{p-(CH₃)₂NH-C₆H₄-NH₃}₂Cl]³⁺. The [BiI₆]³⁻ anions are linked via non-covalent I..I interactions between axial atoms of neighboring anions to form chains running along the c axis of the tetragonal unit cell. In the cationic part, the Cl⁻ anion is involved in four (N)H…Cl hydrogen bonds with hydrogen atoms of the p-(CH₃)₂NH—C₆H₄—NH₃²⁺ cation, forming a two-dimensional substructure. Alternating covalent and I..I halogen bonds in the anionic substructure and cation—anion hydrogen bonds provide the formation of a three-dimensional supramolecular structure with a band gap of 1.93 eV.

Original language	English
Pages (from-to)	39-46
Number of pages	8
Journal	Russian Chemical Bulletin
Volume	70
Issue number	1
DOIs	https://doi.org/10.1007/s11172-021-3054-1
State	Published - Jan 2021

Keywords

Raman spectroscopy
crystal structure
halobismuthates
organic-inorganic hybrid
supramolecular structure

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10.1007/s11172-021-3054-1

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Shestimerova, T. A., Golubev, N. A., Grigorieva, A. V., Bykov, M. A., Wei, Z., Dikarev, E. V., & Shevelkov, A. V. (2021). Supramolecular organization of the organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆]: assembly of a three-dimensional structure via covalent and non-covalent interactions. Russian Chemical Bulletin, 70(1), 39-46. https://doi.org/10.1007/s11172-021-3054-1

@article{a4264b77abea4c10b27bde89fccf2532,

title = "Supramolecular organization of the organic-inorganic hybrid [\{p-(CH3)2NH—C6H4—NH3\}2Cl][BiI6]: assembly of a three-dimensional structure via covalent and non-covalent interactions",

abstract = "A new organic-inorganic hybrid [\{p-(CH3)2NH—C6H4—NH3\}2Cl][BiI6] was synthesized and its crystal structure was established. The hybrid consists of an inorganic anion [BiI6]3− and an organic cation [\{p-(CH3)2NH-C6H4-NH3\}2Cl]3+. The [BiI6]3− anions are linked via non-covalent I..I interactions between axial atoms of neighboring anions to form chains running along the c axis of the tetragonal unit cell. In the cationic part, the Cl− anion is involved in four (N)H…Cl hydrogen bonds with hydrogen atoms of the p-(CH3)2NH—C6H4—NH32+ cation, forming a two-dimensional substructure. Alternating covalent and I..I halogen bonds in the anionic substructure and cation—anion hydrogen bonds provide the formation of a three-dimensional supramolecular structure with a band gap of 1.93 eV.",

keywords = "Raman spectroscopy, crystal structure, halobismuthates, organic-inorganic hybrid, supramolecular structure",

author = "Shestimerova, \{T. A.\} and Golubev, \{N. A.\} and Grigorieva, \{A. V.\} and Bykov, \{M. A.\} and Z. Wei and Dikarev, \{E. V.\} and Shevelkov, \{A. V.\}",

note = "Publisher Copyright: {\textcopyright} 2021, Springer Science+Business Media LLC.",

year = "2021",

month = jan,

doi = "10.1007/s11172-021-3054-1",

language = "English",

volume = "70",

pages = "39--46",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "1",

}

Shestimerova, TA, Golubev, NA, Grigorieva, AV, Bykov, MA, Wei, Z, Dikarev, EV & Shevelkov, AV 2021, 'Supramolecular organization of the organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆]: assembly of a three-dimensional structure via covalent and non-covalent interactions', Russian Chemical Bulletin, vol. 70, no. 1, pp. 39-46. https://doi.org/10.1007/s11172-021-3054-1

Supramolecular organization of the organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆]: assembly of a three-dimensional structure via covalent and non-covalent interactions. / Shestimerova, T. A.; Golubev, N. A.; Grigorieva, A. V. et al.
In: Russian Chemical Bulletin, Vol. 70, No. 1, 01.2021, p. 39-46.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Supramolecular organization of the organic-inorganic hybrid [{p-(CH3)2NH—C6H4—NH3}2Cl][BiI6]

T2 - assembly of a three-dimensional structure via covalent and non-covalent interactions

AU - Shestimerova, T. A.

AU - Golubev, N. A.

AU - Grigorieva, A. V.

AU - Bykov, M. A.

AU - Wei, Z.

AU - Dikarev, E. V.

AU - Shevelkov, A. V.

PY - 2021/1

Y1 - 2021/1

N2 - A new organic-inorganic hybrid [{p-(CH3)2NH—C6H4—NH3}2Cl][BiI6] was synthesized and its crystal structure was established. The hybrid consists of an inorganic anion [BiI6]3− and an organic cation [{p-(CH3)2NH-C6H4-NH3}2Cl]3+. The [BiI6]3− anions are linked via non-covalent I..I interactions between axial atoms of neighboring anions to form chains running along the c axis of the tetragonal unit cell. In the cationic part, the Cl− anion is involved in four (N)H…Cl hydrogen bonds with hydrogen atoms of the p-(CH3)2NH—C6H4—NH32+ cation, forming a two-dimensional substructure. Alternating covalent and I..I halogen bonds in the anionic substructure and cation—anion hydrogen bonds provide the formation of a three-dimensional supramolecular structure with a band gap of 1.93 eV.

AB - A new organic-inorganic hybrid [{p-(CH3)2NH—C6H4—NH3}2Cl][BiI6] was synthesized and its crystal structure was established. The hybrid consists of an inorganic anion [BiI6]3− and an organic cation [{p-(CH3)2NH-C6H4-NH3}2Cl]3+. The [BiI6]3− anions are linked via non-covalent I..I interactions between axial atoms of neighboring anions to form chains running along the c axis of the tetragonal unit cell. In the cationic part, the Cl− anion is involved in four (N)H…Cl hydrogen bonds with hydrogen atoms of the p-(CH3)2NH—C6H4—NH32+ cation, forming a two-dimensional substructure. Alternating covalent and I..I halogen bonds in the anionic substructure and cation—anion hydrogen bonds provide the formation of a three-dimensional supramolecular structure with a band gap of 1.93 eV.

KW - Raman spectroscopy

KW - crystal structure

KW - halobismuthates

KW - organic-inorganic hybrid

KW - supramolecular structure

UR - https://www.scopus.com/pages/publications/85101505195

U2 - 10.1007/s11172-021-3054-1

DO - 10.1007/s11172-021-3054-1

M3 - Article

SN - 1066-5285

VL - 70

SP - 39

EP - 46

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 1

ER -

Supramolecular organization of the organic-inorganic hybrid [{p-(CH₃)₂NH—C₆H₄—NH₃}₂Cl][BiI₆]: assembly of a three-dimensional structure via covalent and non-covalent interactions

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