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Surface and bulk analyses of poly(methyl methacrylate)-poly(vinyl chloride) blends by ESCA, FTIR, and DSC

  • SUNY Buffalo

Research output: Contribution to journalConference articlepeer-review

Abstract

Blending of two homopolymers is a technique often used to obtain a single material possessing desirable characteristics of both component homopolymers. Because of its low cost and versatility, blends of poly(vinyl chloride), PVC, have been extensively studied. The present work examines the four possible binary blends, cast from MEK, of low molecular weight (83,500 PVC; 33,300 PMMA) and high molecular weight (193,600 PVC; 490,200 PMMA) homopolymers. The results show that molecular weight has an effect on blend compatibility and/or surface enrichment. Angle dependent ESCA and ATR-FTIR were used to determine surface compositions and differential scanning calorimetry was used to determine compatibility of the bulk phase.

Original languageEnglish
Pages (from-to)871
Number of pages1
JournalPolymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering
Volume62
StatePublished - 1990
EventProceedings of the ACS Division of Polymeric Materials: Science and Engineering - Boston, MA, USA
Duration: Apr 1 1990Apr 1 1990

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