Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides

Iwao Ojima; Shin Ichi Inaba; Yoichiro Nagai

doi:10.1016/S0022-328X(00)82030-6

Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides

Iwao Ojima
, Shin Ichi Inaba
, Yoichiro Nagai

Chemistry

Stony Brook University

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The hydrosilylation of carbodiimides was found to proceed at higher temperatures in the presence of catalytic amounts of palladium chloride or tris-(triphenylphosphine)chlororhodium to afford N-silylformamidines in high yield. These were found to be good precursors to formamidines and N-acetyl-formamidines.

Original language	English
Pages (from-to)	C11-C13
Journal	Journal of Organometallic Chemistry
Volume	72
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)82030-6
State	Published - Jun 4 1974

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10.1016/S0022-328X(00)82030-6

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title = "Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides",

abstract = "The hydrosilylation of carbodiimides was found to proceed at higher temperatures in the presence of catalytic amounts of palladium chloride or tris-(triphenylphosphine)chlororhodium to afford N-silylformamidines in high yield. These were found to be good precursors to formamidines and N-acetyl-formamidines.",

author = "Iwao Ojima and Inaba, \{Shin Ichi\} and Yoichiro Nagai",

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T1 - Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides

AU - Ojima, Iwao

AU - Inaba, Shin Ichi

AU - Nagai, Yoichiro

PY - 1974/6/4

Y1 - 1974/6/4

N2 - The hydrosilylation of carbodiimides was found to proceed at higher temperatures in the presence of catalytic amounts of palladium chloride or tris-(triphenylphosphine)chlororhodium to afford N-silylformamidines in high yield. These were found to be good precursors to formamidines and N-acetyl-formamidines.

AB - The hydrosilylation of carbodiimides was found to proceed at higher temperatures in the presence of catalytic amounts of palladium chloride or tris-(triphenylphosphine)chlororhodium to afford N-silylformamidines in high yield. These were found to be good precursors to formamidines and N-acetyl-formamidines.

UR - https://www.scopus.com/pages/publications/49549152833

U2 - 10.1016/S0022-328X(00)82030-6

DO - 10.1016/S0022-328X(00)82030-6

M3 - Article

SN - 0022-328X

VL - 72

SP - C11-C13

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Syntheses of N-silylformamidines by the hydrosilylation of carbodiimides

Abstract

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