Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

Fan Zhang; Peter Y. Zavalij; M. Stanley Whittingham

doi:10.1039/a907465a

Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

Fan Zhang
, Peter Y. Zavalij
, M. Stanley Whittingham

Chemistry

Binghamton University

State University of New York Binghamton University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A novel manganese vanadium oxide has been synthesized using the hydrothermal reaction of vanadium(v) pentoxide with manganese(II) sulfate with an organic templating cation at 165°C. The (Mn²⁺)₆(Mn³⁺)(1-2/3z)- (OH)₃(VO₄)₃[(VO₄)(1-2z)(V₂O₇)(z)] (z=0.2) phase has a hexagonal tunnel structure and space group P6₃mc. The cell parameters of this compound are a= 13.229(1) and c= 5.255(1) Å. This compound was also characterized by electron microprobe analysis, FTIR, TGA as well as electrochemically and reacted readily with lithium in electrochemical cells.

Original language	English
Pages (from-to)	3137-3140
Number of pages	4
Journal	Journal of Materials Chemistry
Volume	9
Issue number	12
DOIs	https://doi.org/10.1039/a907465a
State	Published - 1999

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title = "Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction",

abstract = "A novel manganese vanadium oxide has been synthesized using the hydrothermal reaction of vanadium(v) pentoxide with manganese(II) sulfate with an organic templating cation at 165°C. The (Mn2+)6(Mn3+)(1-2/3z)- (OH)3(VO4)3[(VO4)(1-2z)(V2O7)(z)] (z=0.2) phase has a hexagonal tunnel structure and space group P63mc. The cell parameters of this compound are a= 13.229(1) and c= 5.255(1) {\AA}. This compound was also characterized by electron microprobe analysis, FTIR, TGA as well as electrochemically and reacted readily with lithium in electrochemical cells.",

author = "Fan Zhang and Zavalij, \{Peter Y.\} and Whittingham, \{M. Stanley\}",

year = "1999",

doi = "10.1039/a907465a",

language = "English",

volume = "9",

pages = "3137--3140",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

AU - Zhang, Fan

AU - Zavalij, Peter Y.

AU - Whittingham, M. Stanley

PY - 1999

Y1 - 1999

N2 - A novel manganese vanadium oxide has been synthesized using the hydrothermal reaction of vanadium(v) pentoxide with manganese(II) sulfate with an organic templating cation at 165°C. The (Mn2+)6(Mn3+)(1-2/3z)- (OH)3(VO4)3[(VO4)(1-2z)(V2O7)(z)] (z=0.2) phase has a hexagonal tunnel structure and space group P63mc. The cell parameters of this compound are a= 13.229(1) and c= 5.255(1) Å. This compound was also characterized by electron microprobe analysis, FTIR, TGA as well as electrochemically and reacted readily with lithium in electrochemical cells.

AB - A novel manganese vanadium oxide has been synthesized using the hydrothermal reaction of vanadium(v) pentoxide with manganese(II) sulfate with an organic templating cation at 165°C. The (Mn2+)6(Mn3+)(1-2/3z)- (OH)3(VO4)3[(VO4)(1-2z)(V2O7)(z)] (z=0.2) phase has a hexagonal tunnel structure and space group P63mc. The cell parameters of this compound are a= 13.229(1) and c= 5.255(1) Å. This compound was also characterized by electron microprobe analysis, FTIR, TGA as well as electrochemically and reacted readily with lithium in electrochemical cells.

UR - https://www.scopus.com/pages/publications/0032762394

U2 - 10.1039/a907465a

DO - 10.1039/a907465a

M3 - Article

SN - 0959-9428

VL - 9

SP - 3137

EP - 3140

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 12

ER -

Synthesis and characterization of a pipe-structure manganese vanadium oxide by hydrothermal reaction

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