Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions

Tatiana A. Shestimerova; Mikhail A. Bykov; Anastasia V. Grigorieva; Zheng Wei; Evgeny V. Dikarev; Andrei V. Shevelkov

doi:10.1016/j.mencom.2022.03.014

Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions

Tatiana A. Shestimerova
, Mikhail A. Bykov
, Anastasia V. Grigorieva
, Zheng Wei
, Evgeny V. Dikarev
, Andrei V. Shevelkov

Chemistry

University at Albany

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The amantadinium iodoacetatobismuthate(III) [C₁₀H₁₅NH₃·(CH₃)₂CO]₂[BiI_3.67(CH₃COO)_1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI_3.67(CH₃COO)_1.33]^2– and the countercations [C₁₀H₁₅NH₃·(CH₃)₂CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.

Original language	English
Pages (from-to)	194-197
Number of pages	4
Journal	Mendeleev Communications
Volume	32
Issue number	2
DOIs	https://doi.org/10.1016/j.mencom.2022.03.014
State	Published - Mar 1 2022

Keywords

Acetate
Amantadine
Bismuth
Iodide
Perovskite photovoltaics

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10.1016/j.mencom.2022.03.014

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@article{a6b9c1a5cdfe4a979084dcf4fe81b399,

title = "Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions",

abstract = "The amantadinium iodoacetatobismuthate(III) [C10H15NH3·(CH3)2CO]2[BiI3.67(CH3COO)1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI3.67(CH3COO)1.33]2– and the countercations [C10H15NH3·(CH3)2CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.",

keywords = "Acetate, Amantadine, Bismuth, Iodide, Perovskite photovoltaics",

author = "Shestimerova, \{Tatiana A.\} and Bykov, \{Mikhail A.\} and Grigorieva, \{Anastasia V.\} and Zheng Wei and Dikarev, \{Evgeny V.\} and Shevelkov, \{Andrei V.\}",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2022",

month = mar,

day = "1",

doi = "10.1016/j.mencom.2022.03.014",

language = "English",

volume = "32",

pages = "194--197",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Mendeleevskie Soobshcheniya",

number = "2",

}

TY - JOUR

T1 - Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions

AU - Shestimerova, Tatiana A.

AU - Bykov, Mikhail A.

AU - Grigorieva, Anastasia V.

AU - Wei, Zheng

AU - Dikarev, Evgeny V.

AU - Shevelkov, Andrei V.

PY - 2022/3/1

Y1 - 2022/3/1

N2 - The amantadinium iodoacetatobismuthate(III) [C10H15NH3·(CH3)2CO]2[BiI3.67(CH3COO)1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI3.67(CH3COO)1.33]2– and the countercations [C10H15NH3·(CH3)2CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.

AB - The amantadinium iodoacetatobismuthate(III) [C10H15NH3·(CH3)2CO]2[BiI3.67(CH3COO)1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains [BiI3.67(CH3COO)1.33]2– and the countercations [C10H15NH3·(CH3)2CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV.

KW - Acetate

KW - Amantadine

KW - Bismuth

KW - Iodide

KW - Perovskite photovoltaics

UR - https://www.scopus.com/pages/publications/85127346283

U2 - 10.1016/j.mencom.2022.03.014

DO - 10.1016/j.mencom.2022.03.014

M3 - Article

SN - 0959-9436

VL - 32

SP - 194

EP - 197

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 2

ER -

Synthesis and characterization of amantadinium iodoacetatobismuthate, a hybrid compound with mixed iodide–carboxylate anions

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Keywords

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