Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules

Bruce X. Fu; Wenhua Zhang; Benjamin S. Hsiao; Gary Johansson; Bryan B. Sauer; Shawn Phillips; Rusty Balnski; Miriam Rafailovich; Jonathan Sokolov

Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules

Bruce X. Fu
, Wenhua Zhang
, Benjamin S. Hsiao
, Gary Johansson
, Bryan B. Sauer
, Shawn Phillips
, Rusty Balnski
, Miriam Rafailovich
, Jonathan Sokolov

Stony Brook University

Stony Brook University
DuPont
Air Force Research Laboratory

Research output: Contribution to journal › Conference article › peer-review

19 Scopus citations

Abstract

A series of polyurethanes containing different percentages of polyhedral oligomeric silsesquioxanes (POSS) molecules was synthesized and investigated by means of gel permeation chromatography, differential scanning calorimetry and simultaneous wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The DSC scans showed an increase of T_g in the soft segment with the increase in POSS, which suggests an increase in the miscibility between the soft and hard segments, leading to a more uniform polymer matrix with less microphase separation. This was further supported by SAXS results.

Original language	English
Pages (from-to)	587-588
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	41
Issue number	1
State	Published - Mar 2000
Event	The San Francisco Meeting - San Francisco, CA, USA Duration: Mar 26 2000 → Mar 31 2000

Cite this

@article{6a523552ecdc4479a5e8ca4c7950d452,

title = "Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules",

abstract = "A series of polyurethanes containing different percentages of polyhedral oligomeric silsesquioxanes (POSS) molecules was synthesized and investigated by means of gel permeation chromatography, differential scanning calorimetry and simultaneous wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The DSC scans showed an increase of Tg in the soft segment with the increase in POSS, which suggests an increase in the miscibility between the soft and hard segments, leading to a more uniform polymer matrix with less microphase separation. This was further supported by SAXS results.",

author = "Fu, \{Bruce X.\} and Wenhua Zhang and Hsiao, \{Benjamin S.\} and Gary Johansson and Sauer, \{Bryan B.\} and Shawn Phillips and Rusty Balnski and Miriam Rafailovich and Jonathan Sokolov",

year = "2000",

month = mar,

language = "English",

volume = "41",

pages = "587--588",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "1",

note = "The San Francisco Meeting ; Conference date: 26-03-2000 Through 31-03-2000",

}

Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules. / Fu, Bruce X.; Zhang, Wenhua; Hsiao, Benjamin S. et al.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 41, No. 1, 03.2000, p. 587-588.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules

AU - Fu, Bruce X.

AU - Zhang, Wenhua

AU - Hsiao, Benjamin S.

AU - Johansson, Gary

AU - Sauer, Bryan B.

AU - Phillips, Shawn

AU - Balnski, Rusty

AU - Rafailovich, Miriam

AU - Sokolov, Jonathan

PY - 2000/3

Y1 - 2000/3

N2 - A series of polyurethanes containing different percentages of polyhedral oligomeric silsesquioxanes (POSS) molecules was synthesized and investigated by means of gel permeation chromatography, differential scanning calorimetry and simultaneous wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The DSC scans showed an increase of Tg in the soft segment with the increase in POSS, which suggests an increase in the miscibility between the soft and hard segments, leading to a more uniform polymer matrix with less microphase separation. This was further supported by SAXS results.

AB - A series of polyurethanes containing different percentages of polyhedral oligomeric silsesquioxanes (POSS) molecules was synthesized and investigated by means of gel permeation chromatography, differential scanning calorimetry and simultaneous wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The DSC scans showed an increase of Tg in the soft segment with the increase in POSS, which suggests an increase in the miscibility between the soft and hard segments, leading to a more uniform polymer matrix with less microphase separation. This was further supported by SAXS results.

UR - https://www.scopus.com/pages/publications/0033741854

M3 - Conference article

SN - 0032-3934

VL - 41

SP - 587

EP - 588

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 1

T2 - The San Francisco Meeting

Y2 - 26 March 2000 through 31 March 2000

ER -

Synthesis and characterization of novel segmented polyurethanes containing polyhedral oligomeric silsesquioxanes (POSS) nanostructural molecules

Abstract

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