Synthesis and crystal structure of new double mercury silver phosphide iodide Hg12Ag41P88I41

O. S. Oleneva; T. A. Shestimerova; A. V. Olenev; E. V. Dikarev; A. V. Shevelkov

doi:10.1007/s11172-007-0302-y

Synthesis and crystal structure of new double mercury silver phosphide iodide Hg₁₂Ag₄₁P₈₈I₄₁

O. S. Oleneva
, T. A. Shestimerova
, A. V. Olenev
, E. V. Dikarev
, A. V. Shevelkov

Chemistry

University at Albany

Lomonosov Moscow State University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

New double mercury silver phosphide iodide Hg₁₂Ag ₄₁P₈₈I₄₁ (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P₁₁ ^3-, which have been previously found in alkali metal compounds only. The well-ordered P₁₁ ^3- clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.

Original language	English
Pages (from-to)	1948-1952
Number of pages	5
Journal	Russian Chemical Bulletin
Volume	56
Issue number	10
DOIs	https://doi.org/10.1007/s11172-007-0302-y
State	Published - Oct 2007

Keywords

Crystal structure
Disorder
Double mercury silver phosphide iodide
Energy dispersive X-ray analysis
Phosphorus cluster
Synthesis

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10.1007/s11172-007-0302-y

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title = "Synthesis and crystal structure of new double mercury silver phosphide iodide Hg12Ag41P88I41",

abstract = "New double mercury silver phosphide iodide Hg12Ag 41P88I41 (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P11 3-, which have been previously found in alkali metal compounds only. The well-ordered P11 3- clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.",

keywords = "Crystal structure, Disorder, Double mercury silver phosphide iodide, Energy dispersive X-ray analysis, Phosphorus cluster, Synthesis",

author = "Oleneva, \{O. S.\} and Shestimerova, \{T. A.\} and Olenev, \{A. V.\} and Dikarev, \{E. V.\} and Shevelkov, \{A. V.\}",

year = "2007",

month = oct,

doi = "10.1007/s11172-007-0302-y",

language = "English",

volume = "56",

pages = "1948--1952",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

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TY - JOUR

T1 - Synthesis and crystal structure of new double mercury silver phosphide iodide Hg12Ag41P88I41

AU - Oleneva, O. S.

AU - Shestimerova, T. A.

AU - Olenev, A. V.

AU - Dikarev, E. V.

AU - Shevelkov, A. V.

PY - 2007/10

Y1 - 2007/10

N2 - New double mercury silver phosphide iodide Hg12Ag 41P88I41 (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P11 3-, which have been previously found in alkali metal compounds only. The well-ordered P11 3- clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.

AB - New double mercury silver phosphide iodide Hg12Ag 41P88I41 (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P11 3-, which have been previously found in alkali metal compounds only. The well-ordered P11 3- clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.

KW - Crystal structure

KW - Disorder

KW - Double mercury silver phosphide iodide

KW - Energy dispersive X-ray analysis

KW - Phosphorus cluster

KW - Synthesis

UR - https://www.scopus.com/pages/publications/41049111373

U2 - 10.1007/s11172-007-0302-y

DO - 10.1007/s11172-007-0302-y

M3 - Article

SN - 1066-5285

VL - 56

SP - 1948

EP - 1952

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 10

ER -

Synthesis and crystal structure of new double mercury silver phosphide iodide Hg₁₂Ag₄₁P₈₈I₄₁

Abstract

Keywords

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