Synthesis and reactions of H3Ru3(μ3-CSet)(CO)9. Reductive elimination of CH bonds and insertion of alkynes into RuC and RuH bonds

Dennis M. Dalton; Jerome B. Keister

doi:10.1016/0022-328X(85)87305-8

Synthesis and reactions of H₃Ru₃(μ₃-CSet)(CO)₉. Reductive elimination of CH bonds and insertion of alkynes into RuC and RuH bonds

Dennis M. Dalton
, Jerome B. Keister

Chemistry

University at Buffalo

SUNY Buffalo

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Synthesis of H₃Ru₃(μ₃-CSEt)(CO)₉, is accomplished by base-promoted attack of ethanethiol on H₃Ru₃(μ₃-CBr)(CO)₉. Thermolysis of this product under CO yields HRu₃(CH₂SEt)(CO)₉. Reactions of H₃Ru₃(μ₃-CSEt)(CO)₉ with alkynes C₂R₂ form HRu₃(μ₃-η³-EtSCCRCR)(CO)₉ (R = Me or Ph) and Ru₃ (cis-CRCHR)(CSEt)(CO)₉ (R = Me). The chemistry of H₃Ru₃(μ₃-CSEt)(CO)₉ differs significantly from that of the analogous ether derivative H₃Ru₃(μ₃-COMe)(CO)₉.

Original language	English
Pages (from-to)	c37-c40
Journal	Journal of Organometallic Chemistry
Volume	290
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(85)87305-8
State	Published - Aug 6 1985

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title = "Synthesis and reactions of H3Ru3(μ3-CSet)(CO)9. Reductive elimination of CH bonds and insertion of alkynes into RuC and RuH bonds",

abstract = "Synthesis of H3Ru3(μ3-CSEt)(CO)9, is accomplished by base-promoted attack of ethanethiol on H3Ru3(μ3-CBr)(CO)9. Thermolysis of this product under CO yields HRu3(CH2SEt)(CO)9. Reactions of H3Ru3(μ3-CSEt)(CO)9 with alkynes C2R2 form HRu3(μ3-η3-EtSCCRCR)(CO)9 (R = Me or Ph) and Ru3 (cis-CRCHR)(CSEt)(CO)9 (R = Me). The chemistry of H3Ru3(μ3-CSEt)(CO)9 differs significantly from that of the analogous ether derivative H3Ru3(μ3-COMe)(CO)9.",

author = "Dalton, \{Dennis M.\} and Keister, \{Jerome B.\}",

year = "1985",

month = aug,

day = "6",

doi = "10.1016/0022-328X(85)87305-8",

language = "English",

volume = "290",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and reactions of H3Ru3(μ3-CSet)(CO)9. Reductive elimination of CH bonds and insertion of alkynes into RuC and RuH bonds

AU - Dalton, Dennis M.

AU - Keister, Jerome B.

PY - 1985/8/6

Y1 - 1985/8/6

N2 - Synthesis of H3Ru3(μ3-CSEt)(CO)9, is accomplished by base-promoted attack of ethanethiol on H3Ru3(μ3-CBr)(CO)9. Thermolysis of this product under CO yields HRu3(CH2SEt)(CO)9. Reactions of H3Ru3(μ3-CSEt)(CO)9 with alkynes C2R2 form HRu3(μ3-η3-EtSCCRCR)(CO)9 (R = Me or Ph) and Ru3 (cis-CRCHR)(CSEt)(CO)9 (R = Me). The chemistry of H3Ru3(μ3-CSEt)(CO)9 differs significantly from that of the analogous ether derivative H3Ru3(μ3-COMe)(CO)9.

AB - Synthesis of H3Ru3(μ3-CSEt)(CO)9, is accomplished by base-promoted attack of ethanethiol on H3Ru3(μ3-CBr)(CO)9. Thermolysis of this product under CO yields HRu3(CH2SEt)(CO)9. Reactions of H3Ru3(μ3-CSEt)(CO)9 with alkynes C2R2 form HRu3(μ3-η3-EtSCCRCR)(CO)9 (R = Me or Ph) and Ru3 (cis-CRCHR)(CSEt)(CO)9 (R = Me). The chemistry of H3Ru3(μ3-CSEt)(CO)9 differs significantly from that of the analogous ether derivative H3Ru3(μ3-COMe)(CO)9.

UR - https://www.scopus.com/pages/publications/4243621199

U2 - 10.1016/0022-328X(85)87305-8

DO - 10.1016/0022-328X(85)87305-8

M3 - Article

SN - 0022-328X

VL - 290

SP - c37-c40

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Synthesis and reactions of H₃Ru₃(μ₃-CSet)(CO)₉. Reductive elimination of CH bonds and insertion of alkynes into RuC and RuH bonds

Abstract

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