Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethyl acrylate)

Muqian Deng; John T. Welch

doi:10.1007/s10965-023-03824-1

Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ⁶-sulfanyl)ethyl acrylate)

Muqian Deng
, John T. Welch

Chemistry

University at Albany

SUNY Albany

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Tetrafluoro(trifluoromethyl)-λ⁶-sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ⁶-sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.

Original language	English
Article number	443
Journal	Journal of Polymer Research
Volume	30
Issue number	12
DOIs	https://doi.org/10.1007/s10965-023-03824-1
State	Published - Dec 2023

Keywords

Homopolymer, DSC, TGA
Partially fluorinated polymer
Poly acrylate

Access to Document

10.1007/s10965-023-03824-1

Cite this

@article{389248410c1b46b3ba33a8f9c5bf703e,

title = "Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethyl acrylate)",

abstract = "Tetrafluoro(trifluoromethyl)-λ6-sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.",

keywords = "Homopolymer, DSC, TGA, Partially fluorinated polymer, Poly acrylate",

author = "Muqian Deng and Welch, \{John T.\}",

note = "Publisher Copyright: {\textcopyright} 2023, The Polymer Society, Taipei.",

year = "2023",

month = dec,

doi = "10.1007/s10965-023-03824-1",

language = "English",

volume = "30",

journal = "Journal of Polymer Research",

issn = "1022-9760",

publisher = "Springer Netherlands",

number = "12",

}

TY - JOUR

T1 - Synthesis of a novel fluorinated polymer

T2 - poly(2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethyl acrylate)

AU - Deng, Muqian

AU - Welch, John T.

PY - 2023/12

Y1 - 2023/12

N2 - Tetrafluoro(trifluoromethyl)-λ6-sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.

AB - Tetrafluoro(trifluoromethyl)-λ6-sulfanylethyl acrylate, a novel acrylate monomer, was polymerized by initiation with azobisisobutyronitrile (AIBN) at 60 °C to form a soft gel. This novel fluorinated ester was prepared by condensation of excess acryloyl chloride with 2-(tetrafluoro(trifluoromethyl)-λ6-sulfanyl)ethan-1-ol. Thermal decomposition of the polymer begins at 180 °C. Aqueous wetting by static contact measurement yielded a contact angle of 98°.

KW - Homopolymer, DSC, TGA

KW - Partially fluorinated polymer

KW - Poly acrylate

UR - https://www.scopus.com/pages/publications/85177173891

U2 - 10.1007/s10965-023-03824-1

DO - 10.1007/s10965-023-03824-1

M3 - Article

SN - 1022-9760

VL - 30

JO - Journal of Polymer Research

JF - Journal of Polymer Research

IS - 12

M1 - 443

ER -

Synthesis of a novel fluorinated polymer: poly(2-(tetrafluoro(trifluoromethyl)-λ⁶-sulfanyl)ethyl acrylate)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this