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Synthesis of C60-diphenylaminofluorene dyad with large 2PA cross-sections and efficient intramolecular two-photon energy transfer

  • Long Y. Chiang
  • , Prashant A. Padmawar
  • , Taizoon Canteenwala
  • , Loon Seng Tan
  • , Guang S. He
  • , Ramamurthi Kannan
  • , Richard Vaia
  • , Tzu Chau Lin
  • , Qingdong Zheng
  • , Paras N. Prasad
  • University of Massachusetts Lowell
  • National Taiwan University
  • Air Force Research Laboratory
  • SUNY Buffalo

Research output: Contribution to journalArticlepeer-review

57 Scopus citations

Abstract

The first, highly two-photon active C60 derivative comprised of a A-sp3-D conjugate structure was synthesized showing effective two-photon absorption cross-sections (σ2′ = 196×10-48 cm4 sec-1 molecule-1) in the nanosecond regime among the best values for diphenylaminofluorene-based AFX chromophores.

Original languageEnglish
Pages (from-to)1854-1855
Number of pages2
JournalChemical Communications
Issue number17
DOIs
StatePublished - 2002

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