Synthetic ferric sulfate trihydrate, Fe2(SO4) 3·3H2O, a new ferric sulfate salt

Wenqian Xu; John B. Parise

doi:10.1107/S0108270111012273

Synthetic ferric sulfate trihydrate, Fe₂(SO₄) _3·3H₂O, a new ferric sulfate salt

Wenqian Xu
, John B. Parise

Geosciences

Stony Brook University

Stony Brook University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Ferric sulfate trihydrate has been synthesized at 403 K under hydro-thermal conditions. The structure consists of quadruple chains of [Fe ₂(SO₄)₃(H₂O)₃] parallel to [010]. Each quadruple chain is composed of equal proportions of FeO ₄(H₂O)₂ octa-hedra and FeO₅(H ₂O) octa-hedra sharing corners with SO₄ tetra-hedra. The chains are joined to each other by hydrogen bonds. This compound is a new hydration state of Fe₂(SO₄)_3·nH ₂O; minerals with n = 0, 5, 7.25-7.75, 9 and 11 are found in nature.

Original language	English
Pages (from-to)	i30-i32
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	67
Issue number	5
DOIs	https://doi.org/10.1107/S0108270111012273
State	Published - May 2011

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title = "Synthetic ferric sulfate trihydrate, Fe2(SO4) 3·3H2O, a new ferric sulfate salt",

abstract = "Ferric sulfate trihydrate has been synthesized at 403 K under hydro-thermal conditions. The structure consists of quadruple chains of [Fe 2(SO4)3(H2O)3] parallel to [010]. Each quadruple chain is composed of equal proportions of FeO 4(H2O)2 octa-hedra and FeO5(H 2O) octa-hedra sharing corners with SO4 tetra-hedra. The chains are joined to each other by hydrogen bonds. This compound is a new hydration state of Fe2(SO4)3·nH 2O; minerals with n = 0, 5, 7.25-7.75, 9 and 11 are found in nature.",

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AU - Parise, John B.

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N2 - Ferric sulfate trihydrate has been synthesized at 403 K under hydro-thermal conditions. The structure consists of quadruple chains of [Fe 2(SO4)3(H2O)3] parallel to [010]. Each quadruple chain is composed of equal proportions of FeO 4(H2O)2 octa-hedra and FeO5(H 2O) octa-hedra sharing corners with SO4 tetra-hedra. The chains are joined to each other by hydrogen bonds. This compound is a new hydration state of Fe2(SO4)3·nH 2O; minerals with n = 0, 5, 7.25-7.75, 9 and 11 are found in nature.

AB - Ferric sulfate trihydrate has been synthesized at 403 K under hydro-thermal conditions. The structure consists of quadruple chains of [Fe 2(SO4)3(H2O)3] parallel to [010]. Each quadruple chain is composed of equal proportions of FeO 4(H2O)2 octa-hedra and FeO5(H 2O) octa-hedra sharing corners with SO4 tetra-hedra. The chains are joined to each other by hydrogen bonds. This compound is a new hydration state of Fe2(SO4)3·nH 2O; minerals with n = 0, 5, 7.25-7.75, 9 and 11 are found in nature.

UR - https://www.scopus.com/pages/publications/79955621195

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DO - 10.1107/S0108270111012273

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 5

ER -

Synthetic ferric sulfate trihydrate, Fe₂(SO₄) _3·3H₂O, a new ferric sulfate salt

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