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The effect of surface interactions on the viscosity of polymer thin films

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Abstract

Previously, we reported that the viscosity of a polymer film can be measured in situ by observing the liquid-liquid dewetting of polymer bilayer films. In this study, we use the technique to investigate the effect of film thickness and surface interactions on the effective viscosity of polymer thin films. We found that the effective viscosity increases dramatically with decreasing the film thickness. We attribute this to the pinning of the polymer chains at the strongly interacting polymer/Silicon interface.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium Proceedings
Pages197-202
Number of pages6
StatePublished - 2006
Event2005 Materials Research Society Fall Meeting - Boston, MA, United States
Duration: Nov 28 2005Dec 2 2005

Publication series

NameMaterials Research Society Symposium Proceedings
Volume890

Conference

Conference2005 Materials Research Society Fall Meeting
Country/TerritoryUnited States
CityBoston, MA
Period11/28/0512/2/05

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