The effects of Mo alloying and aqueous molybdate on passive film chemistry of stainless steels in chloride solution

R. E. Wistrom; C. R. Clayton; J. C. Lu; D. J. Duquette

The effects of Mo alloying and aqueous molybdate on passive film chemistry of stainless steels in chloride solution

R. E. Wistrom
, C. R. Clayton
, J. C. Lu
, D. J. Duquette

Materials Science and Engineering

Stony Brook University

Research output: Contribution to journal › Article › peer-review

Abstract

Electron spectroscopy for chemical analysis was employed to study the effect of alloyed Mo and aqueous molybdate on the structure and chemistry of passive films formed on ferritic stainless steels in neutral chloride solutions. Results support thermodynamic arguments which explain that Mo6+ incorporation into the film results in an increased O2-)>/OH-)> ratio thus enhancing the films' structural and chemical resistance to Calpha-)> penetration. (A)

Original language	English
Journal	[No source information available]
State	Published - 1989

Cite this

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title = "The effects of Mo alloying and aqueous molybdate on passive film chemistry of stainless steels in chloride solution",

abstract = "Electron spectroscopy for chemical analysis was employed to study the effect of alloyed Mo and aqueous molybdate on the structure and chemistry of passive films formed on ferritic stainless steels in neutral chloride solutions. Results support thermodynamic arguments which explain that Mo6+ incorporation into the film results in an increased O2-)>/OH-)> ratio thus enhancing the films' structural and chemical resistance to Calpha-)> penetration. (A)",

author = "Wistrom, \{R. E.\} and Clayton, \{C. R.\} and Lu, \{J. C.\} and Duquette, \{D. J.\}",

year = "1989",

language = "English",

journal = "[No source information available]",

issn = "0528-4325",

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TY - JOUR

T1 - The effects of Mo alloying and aqueous molybdate on passive film chemistry of stainless steels in chloride solution

AU - Wistrom, R. E.

AU - Clayton, C. R.

AU - Lu, J. C.

AU - Duquette, D. J.

PY - 1989

Y1 - 1989

N2 - Electron spectroscopy for chemical analysis was employed to study the effect of alloyed Mo and aqueous molybdate on the structure and chemistry of passive films formed on ferritic stainless steels in neutral chloride solutions. Results support thermodynamic arguments which explain that Mo6+ incorporation into the film results in an increased O2-)>/OH-)> ratio thus enhancing the films' structural and chemical resistance to Calpha-)> penetration. (A)

AB - Electron spectroscopy for chemical analysis was employed to study the effect of alloyed Mo and aqueous molybdate on the structure and chemistry of passive films formed on ferritic stainless steels in neutral chloride solutions. Results support thermodynamic arguments which explain that Mo6+ incorporation into the film results in an increased O2-)>/OH-)> ratio thus enhancing the films' structural and chemical resistance to Calpha-)> penetration. (A)

UR - https://www.scopus.com/pages/publications/85040956032

M3 - Article

SN - 0528-4325

JO - [No source information available]

JF - [No source information available]

ER -

The effects of Mo alloying and aqueous molybdate on passive film chemistry of stainless steels in chloride solution

Abstract

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