The inserting host-guest system in [N(CH3)4]8(CH3COO)V 22O54.4.25H2O

Thomas Chirayil; Peter Y. Zavalij; M. Stanley Whittingham

doi:10.1107/S0108270198006404

The inserting host-guest system in [N(CH₃)₄]₈(CH₃COO)V ₂₂O₅₄.4.25H₂O

Thomas Chirayil
, Peter Y. Zavalij
, M. Stanley Whittingham

Chemistry

Binghamton University

State University of New York Binghamton University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The title compound, octakis(tetramethylammonium) docosavanadate acetate 4.25-hydrate, was synthesized and found to crystallize in the tetragonal space group P4₂/n. 22 vanadium square pyramids form a barrelshaped cluster which hosts the acetate ion; this is the first case where an organic molecule is hosted by a vanadium oxide cluster. The clusters are linked into a three-dimensional net by hydrogen bonds with water molecules, Tetramethylammonium ions fill the space between the clusters.

Original language	English
Pages (from-to)	1441-1444
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	10
DOIs	https://doi.org/10.1107/S0108270198006404
State	Published - Oct 15 1998

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title = "The inserting host-guest system in [N(CH3)4]8(CH3COO)V 22O54.4.25H2O",

abstract = "The title compound, octakis(tetramethylammonium) docosavanadate acetate 4.25-hydrate, was synthesized and found to crystallize in the tetragonal space group P42/n. 22 vanadium square pyramids form a barrelshaped cluster which hosts the acetate ion; this is the first case where an organic molecule is hosted by a vanadium oxide cluster. The clusters are linked into a three-dimensional net by hydrogen bonds with water molecules, Tetramethylammonium ions fill the space between the clusters.",

author = "Thomas Chirayil and Zavalij, \{Peter Y.\} and Whittingham, \{M. Stanley\}",

year = "1998",

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AU - Chirayil, Thomas

AU - Zavalij, Peter Y.

AU - Whittingham, M. Stanley

PY - 1998/10/15

Y1 - 1998/10/15

N2 - The title compound, octakis(tetramethylammonium) docosavanadate acetate 4.25-hydrate, was synthesized and found to crystallize in the tetragonal space group P42/n. 22 vanadium square pyramids form a barrelshaped cluster which hosts the acetate ion; this is the first case where an organic molecule is hosted by a vanadium oxide cluster. The clusters are linked into a three-dimensional net by hydrogen bonds with water molecules, Tetramethylammonium ions fill the space between the clusters.

AB - The title compound, octakis(tetramethylammonium) docosavanadate acetate 4.25-hydrate, was synthesized and found to crystallize in the tetragonal space group P42/n. 22 vanadium square pyramids form a barrelshaped cluster which hosts the acetate ion; this is the first case where an organic molecule is hosted by a vanadium oxide cluster. The clusters are linked into a three-dimensional net by hydrogen bonds with water molecules, Tetramethylammonium ions fill the space between the clusters.

UR - https://www.scopus.com/pages/publications/0005065293

U2 - 10.1107/S0108270198006404

DO - 10.1107/S0108270198006404

M3 - Article

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JO - Acta Crystallographica Section C: Crystal Structure Communications

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IS - 10

ER -

The inserting host-guest system in [N(CH₃)₄]₈(CH₃COO)V ₂₂O₅₄.4.25H₂O

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