The lowest singlet and triplet states of the oxyallyl diradical

Takatoshi Ichino; Stephanie M. Villano; Adam J. Gianola; Daniel J. Goebbert; Andrei Sanov; Luis Velarde; Stephen J. Blanksby; Xin Zhou; David A. Hrovat; Weston Thatcher Borden; W. Carl Lineberger

doi:10.1002/anie.200904417

The lowest singlet and triplet states of the oxyallyl diradical

Takatoshi Ichino
, Stephanie M. Villano
, Adam J. Gianola
, Daniel J. Goebbert
, Andrei Sanov
, Luis Velarde
, Stephen J. Blanksby
, Xin Zhou
, David A. Hrovat
, Weston Thatcher Borden
, W. Carl Lineberger

Chemistry

University at Buffalo

University of Colorado Boulder
University of Arizona
University of Wollongong
University of North Texas

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

Original language	English
Pages (from-to)	8509-8511
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	45
DOIs	https://doi.org/10.1002/anie.200904417
State	Published - Oct 26 2009

Keywords

Oxyallyl compounds
Photoelectron spectroscopy
Radicals
Reactive intermediates

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10.1002/anie.200904417

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title = "The lowest singlet and triplet states of the oxyallyl diradical",

abstract = "Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.",

keywords = "Oxyallyl compounds, Photoelectron spectroscopy, Radicals, Reactive intermediates",

author = "Takatoshi Ichino and Villano, \{Stephanie M.\} and Gianola, \{Adam J.\} and Goebbert, \{Daniel J.\} and Andrei Sanov and Luis Velarde and Blanksby, \{Stephen J.\} and Xin Zhou and Hrovat, \{David A.\} and Borden, \{Weston Thatcher\} and \{Carl Lineberger\}, W.",

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doi = "10.1002/anie.200904417",

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T1 - The lowest singlet and triplet states of the oxyallyl diradical

AU - Ichino, Takatoshi

AU - Villano, Stephanie M.

AU - Gianola, Adam J.

AU - Goebbert, Daniel J.

AU - Sanov, Andrei

AU - Velarde, Luis

AU - Blanksby, Stephen J.

AU - Zhou, Xin

AU - Hrovat, David A.

AU - Borden, Weston Thatcher

AU - Carl Lineberger, W.

PY - 2009/10/26

Y1 - 2009/10/26

N2 - Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

AB - Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

KW - Oxyallyl compounds

KW - Photoelectron spectroscopy

KW - Radicals

KW - Reactive intermediates

UR - https://www.scopus.com/pages/publications/70350338697

U2 - 10.1002/anie.200904417

DO - 10.1002/anie.200904417

M3 - Article

SN - 1433-7851

VL - 48

SP - 8509

EP - 8511

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 45

ER -

The lowest singlet and triplet states of the oxyallyl diradical

Abstract

Keywords

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