The 115Sn, 117Sn and 119Sn nuclear spin-rotation constants in stannous monoxide, SnO, and a new multi-isotopomer analysis

C. T. Dewberry; K. C. Etchison; G. S. Grubbs; R. A. Powoski; M. M. Serafin; S. A. Peebles; S. A. Cooke

doi:10.1016/j.jms.2007.11.009

The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn nuclear spin-rotation constants in stannous monoxide, SnO, and a new multi-isotopomer analysis

C. T. Dewberry
, K. C. Etchison
, G. S. Grubbs
, R. A. Powoski
, M. M. Serafin
, S. A. Peebles
, S. A. Cooke

School of Natural Sciences & Social Sciences

Purchase College

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J = 1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v = 0, 1, 2, and 3 states. Magnetic hyperfine structure was observed in the transitions for ¹¹⁵Sn¹⁶O, ¹¹⁷Sn¹⁶O and ¹¹⁹Sn¹⁶O. The nuclear spin-rotation constant C_I(Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. A multi-isotopomer analysis, including data from the ¹²⁰Sn¹⁷O and ¹²⁰Sn¹⁸O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

Original language	English
Pages (from-to)	20-25
Number of pages	6
Journal	Journal of Molecular Spectroscopy
Volume	248
Issue number	1
DOIs	https://doi.org/10.1016/j.jms.2007.11.009
State	Published - Mar 2008

Keywords

Hyperfine structure
Rotational spectroscopy
Tin monoxide

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10.1016/j.jms.2007.11.009

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title = "The 115Sn, 117Sn and 119Sn nuclear spin-rotation constants in stannous monoxide, SnO, and a new multi-isotopomer analysis",

abstract = "A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J = 1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v = 0, 1, 2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115Sn16O, 117Sn16O and 119Sn16O. The nuclear spin-rotation constant CI(Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. A multi-isotopomer analysis, including data from the 120Sn17O and 120Sn18O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.",

keywords = "Hyperfine structure, Rotational spectroscopy, Tin monoxide",

author = "Dewberry, \{C. T.\} and Etchison, \{K. C.\} and Grubbs, \{G. S.\} and Powoski, \{R. A.\} and Serafin, \{M. M.\} and Peebles, \{S. A.\} and Cooke, \{S. A.\}",

year = "2008",

month = mar,

doi = "10.1016/j.jms.2007.11.009",

language = "English",

volume = "248",

pages = "20--25",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

number = "1",

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TY - JOUR

T1 - The 115Sn, 117Sn and 119Sn nuclear spin-rotation constants in stannous monoxide, SnO, and a new multi-isotopomer analysis

AU - Dewberry, C. T.

AU - Etchison, K. C.

AU - Grubbs, G. S.

AU - Powoski, R. A.

AU - Serafin, M. M.

AU - Peebles, S. A.

AU - Cooke, S. A.

PY - 2008/3

Y1 - 2008/3

N2 - A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J = 1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v = 0, 1, 2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115Sn16O, 117Sn16O and 119Sn16O. The nuclear spin-rotation constant CI(Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. A multi-isotopomer analysis, including data from the 120Sn17O and 120Sn18O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

AB - A Fourier transform microwave spectrometer has been used to make high resolution measurements on the J = 1-0 rotational transition for 11 isotopomers of SnO. For the most abundant isotopomer the transition was observed in the v = 0, 1, 2, and 3 states. Magnetic hyperfine structure was observed in the transitions for 115Sn16O, 117Sn16O and 119Sn16O. The nuclear spin-rotation constant CI(Sn) has been determined for these isotopomers for the first time and these constants have been related to nmr shielding parameters. A multi-isotopomer analysis, including data from the 120Sn17O and 120Sn18O isotopomers, has been performed on the data. Born-Oppenheimer breakdown parameters were required in the fit and these parameters have been compared to those for the other Sn-chalcogenides.

KW - Hyperfine structure

KW - Rotational spectroscopy

KW - Tin monoxide

UR - https://www.scopus.com/pages/publications/38949107992

U2 - 10.1016/j.jms.2007.11.009

DO - 10.1016/j.jms.2007.11.009

M3 - Article

SN - 0022-2852

VL - 248

SP - 20

EP - 25

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 1

ER -

The ¹¹⁵Sn, ¹¹⁷Sn and ¹¹⁹Sn nuclear spin-rotation constants in stannous monoxide, SnO, and a new multi-isotopomer analysis

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Keywords

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