Transition-metal complexes of an open geodesic polyarene

Marina A. Petrukhina; Kristian W. Andreini; James Mack; Lawrence T. Scott

doi:10.1002/anie.200351403

Transition-metal complexes of an open geodesic polyarene

Marina A. Petrukhina
, Kristian W. Andreini
, James Mack
, Lawrence T. Scott

Chemistry

University at Albany

SUNY Albany
Boston College

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

Corannulene, the smallest subunit of C60 that retains a curved surface, forms crystalline η²-coordinated π complexes with dirhodium(II) tetrakis(trifluoroacetate) by using solvent-free gas-phase deposition. As many as three metal atoms coordinate to the double bonds found at the rim of each corannulene, with one such atom always located on the concave surface (see picture).

Original language	English
Pages (from-to)	3375-3379
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	29
DOIs	https://doi.org/10.1002/anie.200351403
State	Published - Jul 28 2003

Keywords

Aromaticity
Carboxylates
Corannulene
Pi interactions
Rhodium
Structure elucidation

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10.1002/anie.200351403

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title = "Transition-metal complexes of an open geodesic polyarene",

abstract = "Corannulene, the smallest subunit of C60 that retains a curved surface, forms crystalline η2-coordinated π complexes with dirhodium(II) tetrakis(trifluoroacetate) by using solvent-free gas-phase deposition. As many as three metal atoms coordinate to the double bonds found at the rim of each corannulene, with one such atom always located on the concave surface (see picture).",

keywords = "Aromaticity, Carboxylates, Corannulene, Pi interactions, Rhodium, Structure elucidation",

author = "Petrukhina, \{Marina A.\} and Andreini, \{Kristian W.\} and James Mack and Scott, \{Lawrence T.\}",

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language = "English",

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T1 - Transition-metal complexes of an open geodesic polyarene

AU - Petrukhina, Marina A.

AU - Andreini, Kristian W.

AU - Mack, James

AU - Scott, Lawrence T.

PY - 2003/7/28

Y1 - 2003/7/28

N2 - Corannulene, the smallest subunit of C60 that retains a curved surface, forms crystalline η2-coordinated π complexes with dirhodium(II) tetrakis(trifluoroacetate) by using solvent-free gas-phase deposition. As many as three metal atoms coordinate to the double bonds found at the rim of each corannulene, with one such atom always located on the concave surface (see picture).

AB - Corannulene, the smallest subunit of C60 that retains a curved surface, forms crystalline η2-coordinated π complexes with dirhodium(II) tetrakis(trifluoroacetate) by using solvent-free gas-phase deposition. As many as three metal atoms coordinate to the double bonds found at the rim of each corannulene, with one such atom always located on the concave surface (see picture).

KW - Aromaticity

KW - Carboxylates

KW - Corannulene

KW - Pi interactions

KW - Rhodium

KW - Structure elucidation

UR - https://www.scopus.com/pages/publications/0042029708

U2 - 10.1002/anie.200351403

DO - 10.1002/anie.200351403

M3 - Article

SN - 1433-7851

VL - 42

SP - 3375

EP - 3379

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Transition-metal complexes of an open geodesic polyarene

Abstract

Keywords

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