Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines

Jianhua Guo; Andreas Mayr

doi:10.1016/S0020-1693(97)05459-5

Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines

Jianhua Guo
, Andreas Mayr

Chemistry

Stony Brook University

Stony Brook University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The complexes trans-[FeI₂(CN-3-pyridyl)₄], trans-[PdI₂(CNR)₂] (CNR = 2-, 3- and 4-isocyanopyridine, 3-isocyanoquinoline, 4-isocyanoquinaldine, 5-isocyanoquinoline, 5-isocyanoisoquinoline) and trans-[PtI₂(CNR)₂] (CNR = 3-isocyanopyridine,5-isocyanoquinoline) were prepared. The new complexes are thermally stable up to 150°C or higher. The molecular structure of trans-[PdI₂(CN-3-quinolyl)₂] was determined by X-ray crystallography: monoclinic space group P2₁/c, a = 5.8381 (5), b = 23.685(2), c = 7.2122(6) Å, β = 97.628(8)°, Z = 2, 1170 unique reflections, R = 0.035, R_w = 0.035. In the crystal, the molecular units are packed to form two-dimensional sheets which are held together by π stacking of the 3-quinolyl groups.

Original language	English
Pages (from-to)	141-146
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	261
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(97)05459-5
State	Published - Sep 15 1997

Keywords

Crystal structures
Isocyanoisoquinoline complexes
Isocyanopyridine complexes
Isocyanoquinoline complexes
Transition metal complexes

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10.1016/S0020-1693(97)05459-5

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@article{6ab6072282d1457cb340ef8c4caa3100,

title = "Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines",

abstract = "The complexes trans-[FeI2(CN-3-pyridyl)4], trans-[PdI2(CNR)2] (CNR = 2-, 3- and 4-isocyanopyridine, 3-isocyanoquinoline, 4-isocyanoquinaldine, 5-isocyanoquinoline, 5-isocyanoisoquinoline) and trans-[PtI2(CNR)2] (CNR = 3-isocyanopyridine,5-isocyanoquinoline) were prepared. The new complexes are thermally stable up to 150°C or higher. The molecular structure of trans-[PdI2(CN-3-quinolyl)2] was determined by X-ray crystallography: monoclinic space group P21/c, a = 5.8381 (5), b = 23.685(2), c = 7.2122(6) {\AA}, β = 97.628(8)°, Z = 2, 1170 unique reflections, R = 0.035, Rw = 0.035. In the crystal, the molecular units are packed to form two-dimensional sheets which are held together by π stacking of the 3-quinolyl groups.",

keywords = "Crystal structures, Isocyanoisoquinoline complexes, Isocyanopyridine complexes, Isocyanoquinoline complexes, Transition metal complexes",

author = "Jianhua Guo and Andreas Mayr",

year = "1997",

month = sep,

day = "15",

doi = "10.1016/S0020-1693(97)05459-5",

language = "English",

volume = "261",

pages = "141--146",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier B.V.",

number = "2",

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TY - JOUR

T1 - Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines

AU - Guo, Jianhua

AU - Mayr, Andreas

PY - 1997/9/15

Y1 - 1997/9/15

N2 - The complexes trans-[FeI2(CN-3-pyridyl)4], trans-[PdI2(CNR)2] (CNR = 2-, 3- and 4-isocyanopyridine, 3-isocyanoquinoline, 4-isocyanoquinaldine, 5-isocyanoquinoline, 5-isocyanoisoquinoline) and trans-[PtI2(CNR)2] (CNR = 3-isocyanopyridine,5-isocyanoquinoline) were prepared. The new complexes are thermally stable up to 150°C or higher. The molecular structure of trans-[PdI2(CN-3-quinolyl)2] was determined by X-ray crystallography: monoclinic space group P21/c, a = 5.8381 (5), b = 23.685(2), c = 7.2122(6) Å, β = 97.628(8)°, Z = 2, 1170 unique reflections, R = 0.035, Rw = 0.035. In the crystal, the molecular units are packed to form two-dimensional sheets which are held together by π stacking of the 3-quinolyl groups.

AB - The complexes trans-[FeI2(CN-3-pyridyl)4], trans-[PdI2(CNR)2] (CNR = 2-, 3- and 4-isocyanopyridine, 3-isocyanoquinoline, 4-isocyanoquinaldine, 5-isocyanoquinoline, 5-isocyanoisoquinoline) and trans-[PtI2(CNR)2] (CNR = 3-isocyanopyridine,5-isocyanoquinoline) were prepared. The new complexes are thermally stable up to 150°C or higher. The molecular structure of trans-[PdI2(CN-3-quinolyl)2] was determined by X-ray crystallography: monoclinic space group P21/c, a = 5.8381 (5), b = 23.685(2), c = 7.2122(6) Å, β = 97.628(8)°, Z = 2, 1170 unique reflections, R = 0.035, Rw = 0.035. In the crystal, the molecular units are packed to form two-dimensional sheets which are held together by π stacking of the 3-quinolyl groups.

KW - Crystal structures

KW - Isocyanoisoquinoline complexes

KW - Isocyanopyridine complexes

KW - Isocyanoquinoline complexes

KW - Transition metal complexes

UR - https://www.scopus.com/pages/publications/0006959949

U2 - 10.1016/S0020-1693(97)05459-5

DO - 10.1016/S0020-1693(97)05459-5

M3 - Article

SN - 0020-1693

VL - 261

SP - 141

EP - 146

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines

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Keywords

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