Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films

Ruilan Xu; Yong Peng; Peng Lu; Yurun Miao; Xuekui Duan; Dennis T. Lee; Rui Wang; Zhengbao Wang; Michael Tsapatsis

doi:10.1039/d2ce01407f

Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films

Ruilan Xu
, Yong Peng
, Peng Lu
, Yurun Miao
, Xuekui Duan
, Dennis T. Lee
, Rui Wang
, Zhengbao Wang
, Michael Tsapatsis

Materials Science and Engineering

Stony Brook University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The presence of MFI twin crystals on b-axis oriented zeolite MFI nanosheet films was suppressed by adding dihydroxy-benzene isomers in the synthesis mixture. The resulting nanosheet films exhibit good intergrowth and a small grain thickness of 30-45 nm within a relatively short synthesis time (hours). The possible twin suppression mechanisms for the three isomers are discussed.

Original language	English
Pages (from-to)	2359-2365
Number of pages	7
Journal	CrystEngComm
Volume	25
Issue number	16
DOIs	https://doi.org/10.1039/d2ce01407f
State	Published - Mar 24 2023

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title = "Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films",

abstract = "The presence of MFI twin crystals on b-axis oriented zeolite MFI nanosheet films was suppressed by adding dihydroxy-benzene isomers in the synthesis mixture. The resulting nanosheet films exhibit good intergrowth and a small grain thickness of 30-45 nm within a relatively short synthesis time (hours). The possible twin suppression mechanisms for the three isomers are discussed.",

author = "Ruilan Xu and Yong Peng and Peng Lu and Yurun Miao and Xuekui Duan and Lee, \{Dennis T.\} and Rui Wang and Zhengbao Wang and Michael Tsapatsis",

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T1 - Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films

AU - Xu, Ruilan

AU - Peng, Yong

AU - Lu, Peng

AU - Miao, Yurun

AU - Duan, Xuekui

AU - Lee, Dennis T.

AU - Wang, Rui

AU - Wang, Zhengbao

AU - Tsapatsis, Michael

PY - 2023/3/24

Y1 - 2023/3/24

N2 - The presence of MFI twin crystals on b-axis oriented zeolite MFI nanosheet films was suppressed by adding dihydroxy-benzene isomers in the synthesis mixture. The resulting nanosheet films exhibit good intergrowth and a small grain thickness of 30-45 nm within a relatively short synthesis time (hours). The possible twin suppression mechanisms for the three isomers are discussed.

AB - The presence of MFI twin crystals on b-axis oriented zeolite MFI nanosheet films was suppressed by adding dihydroxy-benzene isomers in the synthesis mixture. The resulting nanosheet films exhibit good intergrowth and a small grain thickness of 30-45 nm within a relatively short synthesis time (hours). The possible twin suppression mechanisms for the three isomers are discussed.

UR - https://www.scopus.com/pages/publications/85153340573

U2 - 10.1039/d2ce01407f

DO - 10.1039/d2ce01407f

M3 - Article

SN - 1466-8033

VL - 25

SP - 2359

EP - 2365

JO - CrystEngComm

JF - CrystEngComm

IS - 16

ER -

Twin suppression effect of dihydroxy-benzene isomers during the secondary growth of b-oriented zeolite MFI nanosheet films

Abstract

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