Unprecedented complexation of two transition metals to the concave surface of a geodesic polyarene: {[Rh 2 (O 2CCF 3) 4] 3 (dibenzo[a,g]corannulene) 2}

Marina A. Petrukhina; Kristian W. Andreini; Vikki M. Tsefrikas; Lawrence T. Scott

doi:10.1021/om040131z

Unprecedented complexation of two transition metals to the concave surface of a geodesic polyarene: {[Rh ₂ (O ₂CCF ₃) ₄] ₃ (dibenzo[a,g]corannulene) ₂}

Marina A. Petrukhina
, Kristian W. Andreini
, Vikki M. Tsefrikas
, Lawrence T. Scott

Chemistry

University at Albany

SUNY Albany
Boston College

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

X-ray structural characterization of the bowl-shaped dibenzo[a,g] corannulene, C ₂₈H ₁₄, and its first transition-metal complex, {[RA ₂(O ₂CCF ₃) ₄] ₃(C ₂₈H ₁₄) ₂}, has been accomplished. The latter exhibits a novel one-dimensional extended structure based on the tridentate η ²:η ²η ² rim coordination of dibenzo[a,g]corannulene. The large concave surface area of C ₂₈H ₁₄ allows for the first time two metal units to be endo-coordinated to a geodesic polyarene.

Original language	English
Pages (from-to)	1394-1397
Number of pages	4
Journal	Organometallics
Volume	24
Issue number	7
DOIs	https://doi.org/10.1021/om040131z
State	Published - Mar 28 2005

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title = "Unprecedented complexation of two transition metals to the concave surface of a geodesic polyarene: \{[Rh 2 (O 2CCF 3) 4] 3 (dibenzo[a,g]corannulene) 2\}",

abstract = "X-ray structural characterization of the bowl-shaped dibenzo[a,g] corannulene, C 28H 14, and its first transition-metal complex, \{[RA 2(O 2CCF 3) 4] 3(C 28H 14) 2\}, has been accomplished. The latter exhibits a novel one-dimensional extended structure based on the tridentate η 2:η 2η 2 rim coordination of dibenzo[a,g]corannulene. The large concave surface area of C 28H 14 allows for the first time two metal units to be endo-coordinated to a geodesic polyarene.",

author = "Petrukhina, \{Marina A.\} and Andreini, \{Kristian W.\} and Tsefrikas, \{Vikki M.\} and Scott, \{Lawrence T.\}",

year = "2005",

month = mar,

day = "28",

doi = "10.1021/om040131z",

language = "English",

volume = "24",

pages = "1394--1397",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Unprecedented complexation of two transition metals to the concave surface of a geodesic polyarene

T2 - {[Rh 2 (O 2CCF 3) 4] 3 (dibenzo[a,g]corannulene) 2}

AU - Petrukhina, Marina A.

AU - Andreini, Kristian W.

AU - Tsefrikas, Vikki M.

AU - Scott, Lawrence T.

PY - 2005/3/28

Y1 - 2005/3/28

N2 - X-ray structural characterization of the bowl-shaped dibenzo[a,g] corannulene, C 28H 14, and its first transition-metal complex, {[RA 2(O 2CCF 3) 4] 3(C 28H 14) 2}, has been accomplished. The latter exhibits a novel one-dimensional extended structure based on the tridentate η 2:η 2η 2 rim coordination of dibenzo[a,g]corannulene. The large concave surface area of C 28H 14 allows for the first time two metal units to be endo-coordinated to a geodesic polyarene.

AB - X-ray structural characterization of the bowl-shaped dibenzo[a,g] corannulene, C 28H 14, and its first transition-metal complex, {[RA 2(O 2CCF 3) 4] 3(C 28H 14) 2}, has been accomplished. The latter exhibits a novel one-dimensional extended structure based on the tridentate η 2:η 2η 2 rim coordination of dibenzo[a,g]corannulene. The large concave surface area of C 28H 14 allows for the first time two metal units to be endo-coordinated to a geodesic polyarene.

UR - https://www.scopus.com/pages/publications/16244377774

U2 - 10.1021/om040131z

DO - 10.1021/om040131z

M3 - Article

SN - 0276-7333

VL - 24

SP - 1394

EP - 1397

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Unprecedented complexation of two transition metals to the concave surface of a geodesic polyarene: {[Rh ₂ (O ₂CCF ₃) ₄] ₃ (dibenzo[a,g]corannulene) ₂}

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